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Typical Photochemical Processes
Chemistry
Aqueous dispersion of polymers that can be solidified into rubber (Latex)
Falling -Film Photoreactors
Bleaching
Falling -Film Photoreactors
Brominated intermediates for synthesis (e.g. substituted benzylbromides)
Side-Loop Photoreactors
Chlorinated intermediates for synthesis (e.g. benzylchloride, benzalchloride, methylchloride)
Side-Loop Photoreactors
Chlorinated solvents (e.g. dichloromethane, chloroform, tetrachloromethane)
Side-Loop Photoreactors
Fluorinations, Sulfoxidations, Nitrosylations
Side-Loop Photoreactors
Fragerances (e.g. Rose Oxyde via Singlet Oxygen Reaction)
Plug-Flow Photoreactors
Fragrances (e.g. singlet oxygen reaction: Rose oxide)
Side-Loop Photoreactors
Intermediates for diagnostics (e.g. by photo- bromination or photo-iodination)
Side-Loop Photoreactors
Lubricants (e.g. Fomblin)
Side-Loop Photoreactors
Material modifications (processes in heterogeneous – liquid/liquid and solid/liquid – media (e.g. chlorinated rubbers, chlorinated PVC (C-PVC))
Agitated Photoreactors
Mercaptan synthesis (e.g. Cyclohexylthiol via H2S addition)
Plug-Flow Photoreactors
Monomer modification
Falling -Film Photoreactors
Nitrosylations
Agitated Photoreactors
Photocatalyzed and photo-redox processes (processes in heterogeneous – solid/liquid – media)
Agitated Photoreactors
Photohalogenations
Agitated Photoreactors
Photooxidations implying radical intermediates (e.g. AOP)
Falling -Film Photoreactors
Photopolymerizations (radical and cationic) in heterogeneous – liquid/liquid and solid/liquid – media) (e.g. Caprolactam as pre-cursor of Nylon 6, Lauryllactam as pre-cursor of Nylon 12, Polyacrylates, Polystyrenes and co-polymers, mini-emulsions with monomer functionalization)
Agitated Photoreactors
Plant treatment intermediates (e.g. pinacols by photo-hydrodimerisation)
Side-Loop Photoreactors
Polymer and co-polymer specialities (photopolymerization in homogeneous (liquid), heterogeneous (liquid/liquid and liquid/gas (aerosols) media)
Side-Loop Photoreactors
Preparative photochemistry in general implying strongly absorbing substrates and/or radical imtermediates
Falling -Film Photoreactors
Recovery of precious metals
Falling -Film Photoreactors
Safety agents (e.g. odour additives for gases)
Side-Loop Photoreactors
Sulfoxidations and sulfochlorinations (e.g. Sulphochlorinate polyethylene)
Agitated Photoreactors
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